Airborne hexavalent chromium is a known human respiratory carcinogen and allergen. Many workers are exposed to hexavalent chromium in various processes which chromium electroplating plants are the most common. In this study, the feasibility of a new control approach to remove this pollutant using chitosan beads as a biosorbent was investigated. Hexavalent chromium sorption was studied relative to pH, pollution concentration, sorbent concentration, temperature, and air velocity using one factor at a time approach and Taguchi experimental design. Polluted air with different chromium mist concentrations (10-5000 �g/m3) was contacted to chitosan beads (3.3-20 g/L), floating in distilled water with adjusted pH (3-7), using an impinger at different temperatures (20 and 35 �C), and various velocities (1.12 and 2.24 m/s). The ANOVA test result showed that, there were statistical significant differences between factor levels except optimized pH levels. The higher ions removal efficiencies were achieved at lower levels of air velocities, pollution concentrations, and higher levels of solution pH values, temperatures, and sorbent concentrations.
Ahalya, N.; Kanamadi, R. D.; Ramachanda, T. V., (2005). Biosorption of chromium (VI) from aqueous solutions by the husk of Bangal gram (Cicer arientium). J. Biotechnol., 8 (3), 258-264 (7 Pages), DOI: 10.2225/vol8-issue3-fulltext-10.. Full Text (314 K)
2.
Araujo, M. M.; Teixeira, J. A., (1997). Trivalent chromium sorption on alginate beads. Int. Biodeterior. Biodegrad., 40 (1), 63-74 (12 Pages), DOI: 10.1016/S0964-8305(97)00064-4. Abstract | Full Text (1094 K)
3.
Ashley, K.; Howe, A. M.; Demang, M.; Nygren, O., (2003). Sampling and analysis consideration for the determination of hexavalent chromium in workplace air. J. Environ. Monit., 5 (5), 707-716 (10 Pages)Abstract | Full Text
4.
Boddu, V. M.; Smoth, E. D., (2002). A composite chitosan biosorbent for adsorption of heavy metals from wastewaters.
5.
Chand, S.; Agarwal, V. K.; Kumar, P., (1994). Removal of hexavalent chromium from wastewater by adsorption. Indian J. Environ. Health., 36 (3), 151-158 (8 Pages)
6.
Cornelis, R., (1994). Chromium in Herber R.F.M Stoeppler M. Trace element analysis in biological. Elsevier science, Nederland, Chapter 16, , 343-349 (7 Pages)
7.
Dzul Erosa, M. S.; Saucedo Medina, T. I.; Navaro Mendoza, R.; Avila Rodrguez, M.; Guibal, E., (2001). Cadminm sorption on chitosan sorbents: kinetic and equilibrium studies. Hydrometallurgy, 61 (3), 157-167 (11 Pages), DOI: 10.1016/S0304-386X(01)00166-9. Abstract | Full Text (210 K)
8.
Gibb, H. J.; Lees, P. S.; Pinsky, P. F.; Rooney, B. C., (2000). Lung cancer exposure-response among chromium production workers. Am. J. Ind. Med., 38 (2), 115-126 (12 Pages), DOI: 10.1002/1097-0274(200008)38:2<115::AID-AJIM1>3.0.CO;2-Y. Abstract | Full Text (162 K)
9.
Guibal, E. Von Offenberg Sweeney, N. Zikan, M.C. Vincent, T.; Tobin, J. M., (2001). Comparative sorption of platinum and palladium on chitosan derivatives. Int. J. Biologic. Macromol., 28 (5), 401-408 (8 Pages), DOI: 10.1016/S0141-8130(01)00130-1. Abstract | Full Text (157 K)
10.
Guibal, E.; Milot, C.; Tobin, J. M., (1998). Metal-anion sorption by chitosan beads: equilibrium a kinetic studies. Ind. Eng. Chem. Res., 37 (4), 1454-1463 (10 Pages), DOI: 10.1021/ie9703954. Abstract | Full Text (115 K)
11.
Guibal, E.; Vincent, T.; Navarro Mendoza, R., (2000). Synthesis and characterization of a thiourea derivative of chitosan for platinum recovery. J. Appl. Polym. Sci., 75 (1), 119-134 (16 Pages)Abstract | Full Text (282 K)
12.
Jansson-charrier, M.; Guibal, E.; Roussy, J.; Delanghe, B.; Le Cloirec, P., (1996). Vanadium (IV) sorption by chitosan: kinetic and equilibrium. Wat. Res., 30 (2), 467-475 (9 Pages), DOI: 10.1016/0043-1354(95)00154-9. Abstract | Full Text (963 K)
Mancuso, T. F., (1997). Chromium as an industrial carcinogen. Part I. Am. J. Ind. Med., 31 (2), 129-139 (11 Pages), DOI: 10.1002/(SICI)1097-0274(199702)31:2<129::AID-AJIM1>3.0.CO;2-V. Abstract | Full Text (137 K)
15.
Merroun, M. L.; Ben Omar, M.; Gonzalez-Munoz, M. T.; Arias, J. M., (1998). Myxococcus Xanthus biomass as biosorbent for lead. J. Appl. Mmicrobiol., 84 (1), 63-67 (5 Pages), DOI: 10.1046/j.1365-2672.1997.00303.x. Abstract | Full Text (224 K)
16.
Schmuhl, R.; Krieg, H. M.; Keizer, K., (2001). Adsorption of Cu (II) and Cr (VI) ions by chitosan: kinetic and equilibrium studies. Water S.A., 27 (1), 1-8 (8 Pages)Abstract | Full Text
17.
Sheehan, P.; Ricks, R.; Ripple, S.; Paustenbach, D., (1992). Field evaluation of a sampling and analytical method for environmental level of airborne hexavalen chromium. Am. Ind. Hyg. Assoc. J., 53 (1), 57-68 (12 Pages)Abstract
18.
Tirgar, A.; Golbabei, F.; Nourijelyani, K.; Shahtaheri, S. J.; Ganjali, M. R.; Hamedi, J., (2006). Design and performance of chromium mist generator. J. Braz. Chem. Soc., 17 (2), 342-347 (6 Pages), DOI: 10.1590/S0103-50532006000200018.. Full Text