The kinetic and thermodynamic of the bath sorption of lead (Pb) on to activated carbon from Coconut (CA) and Seed hull of the Palm tree (GA) have been investigated. The effects of initial Pb concentration, contact time and temperature were examined. The results showed that the adsorption capacities of the activated carbons increased with the initial lead concentration. The process sorption followed a pseudo first order kinetics and parameters such as Ea and k0 were determined. It could be best fitted by the Langmuir and Freundlich isotherms. From the first, the equilibrium sorption capacities of lead ion were determined and found to be respectively 4.38 and 3.77 mg/g for CA and GA at 60 �C. The thermodynamic parameters such as ?H, ?S and ?G were computed from the experimental data. These values show that the adsorption is endothermic and non spontaneous. Moreover, the relative weak values of ?H (~5 kcal/mol) confirm a physical adsorption. The maximum adsorptions were obtained at 60 �C, pH 4 and with a Pb initial concentration of 100 mg/L.
Assenato, G., Paci, C., Baser, M.C., Molinini, R., Candela, R. M., Altamura B.M., Giorgino, R., (1986). Sperm count suppression without endocrine dysfunction in lead-exposed men. Arch. Environ. Health., 4, 387-390 (4 Pages)
2.
Carrasquero Duran, A., Flores, I., Perozo, C and Pernalete, S., (2006). Immobilization of lead by vermicompost an its
effect on white bean (Vigna Sinenis var. Apure) uptake. Int. J. Environ. Sci. Tech., 3 (3), 203-212 (10 Pages)
3.
Freundlich, H.M.F., (1906). Uber die adsorption in losungen. Z. Phys. Chem., 57 A, 385-470 (86 Pages)
4.
Goyer R.A., Chisolon, I.J., (1972). Lead in metallic contaminations and human health. Lee, D.H.K. (Ed). Academic Press, New York., , 57-57 (1 Page)
5.
Gueu, S., Yao, B, Adouby, K., Ado, G., (2006). Heavy metals removal in aqueous solution by activated carbons prepared from coconut shell and seed shell of the palm tree. J. Appl.Sci., 6 (13), 2789-2793 (5 Pages)
6.
Ho, Y.S., Ofomaja, A.E., (2005). Kinetics and thermodynamics of lead ion sorption on palm kermel fibre from aqueous
solution. Proc. Biochem., 40, 3455-3461 (7 Pages)
7.
Krishnan, K.A., Anirudhan T.S., (2003). Removal of cadmium (II) from solutions by steam-activated sulphurised carbon
prepared from sugar-cane bagasse pith: Kinetics and equilibrium studies. Water SA., 29 (2), 147-156 (10 Pages)
8.
Lagergren, S., (1988). Zur theorie der sogenannten adsorption
gelöster stoffe, Kungliga Svenska Vetenskapsakademiens. Handlingar., 24 (4), 1-39 (39 Pages)
9.
Langmuir, I., (1916). The constitution and fundamental properties of solids and liquids. J. Am. Chem. Soc., 38 (11), 2221-2295 (75 Pages), DOI: 10.1021/ja02254a006. Abstract | Full Text (3844 K)
10.
Serkar, M., Sakthi, V. and Rengaraj, S., (2004). Kinetics and equilibrium adsorption study of lead (II) onto activated carbon prepared from coconut shell. J. Coll. Inter. Sci., 279 (2), 307-307 (1 Page)
11.
Sreedhar, M.K., Madhukumar, A., Anirudhan, T.S., (1999). Evaluation of an adsorbent prepared by treating coconut husk with polysulphide for the removal of mercury from wastewater. Indian J. Eng. Mater. Sci., 6 (5), 279-285 (7 Pages)